van Rijssel, Erwin R.; Goumans, Theodorus P. M.; Lodder, Gerrit; Overkleeft, Herman S.; van der Marel, Gijsbert A.; Codee, Jeroen D. C. published the artcile< Chiral Pyrroline-Based Ugi-Three-Component Reactions Are under Kinetic Control>, Application of C19H34O2, the main research area is chiral pyrroline Ugi kinetic control.
Although it is often assumed that the stereochem. in Ugi multicomponent reactions is determined in the final Mumm rearrangement step, exptl. and computational evidence that Ugi reactions on hydroxylated pyrrolines proceed under kinetic control is reported. The stereochem. of the reaction is established with the addition of the isocyanide to the intermediate iminium ion, whose conformation is determined by its substitution pattern.
Organic Letters published new progress about Addition reaction, stereoselective (isocyanide). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application of C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics