Li, Fang-Fang; Ma, Jian-Fang; Yang, Jin; Jia, Heng-Qing; Hu, Ning-Hai published the artcile< Syntheses, structures and luminescence of silver(I) sulfonate complexes with PPh3 ligand>, Computed Properties of 112-63-0, the main research area is silver sulfonate phosphine preparation structure luminescence; crystal structure silver arylsulfonato phosphine complex.
Four new luminescent silver(I) sulfonate complexes with PPh3, Ag(L1)(PPh3)2 (1), Ag(L2)(PPh3)3 (2), [Ag2(L3)(PPh3)4(H2O)]·1.5CH3CN·0.5H2O (3) and [Ag4(L4)(PPh3)10]·8H2O (4), where L1 = p-toluenesulfonate, L2 = 1-naphthalenesulfonate, L3 = 3-carboxylate-4-hydroxybenzenesulfonate, L4 = 1,3,6,8-pyrenetetrasulfonate and PPh3 = triphenylphosphine, were synthesized and characterized. The crystal structures were determined by single-crystal x-ray diffraction method. Compounds 1, 2, 3 and 4 adopt discrete structures rather than polymeric structures. Compounds 1 and 2 show mononuclear structures while 3 and 4 are dinuclear and tetranuclear mols., resp. Also the numbers of PPh3 mols. coordinating to one silver center are two or three. The photoluminescent properties of 1, 2 and 3 are discussed.
Journal of Molecular Structure published new progress about Crystal structure. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Computed Properties of 112-63-0.
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