Kisel, V. M.; Kovtunenko, V. A.; Turov, A. V.; Tyltin, A. K.; Babichev, F. S. published the artcile< Synthesis and properties of new dibenz[b,f]azocine functional derivatives>, Computed Properties of 112-63-0, the main research area is Thorpe reaction oxycyanodibenzazocine dibromoacetophenone; acetophenone dibromo Thorpe reaction oxycyanodibenzazocine; intramol cyclocondensation acylcyanomethylbenzylanthranilate; anthranilate acylcyanomethylbenzyl intramol cyclocondensation; dibenzazocine oxycyano Thorpe reaction dibromoacetophenone; azocine oxycyanodibenz Thorpe reaction dibromoacetophenone; furoazocine dibenz.
The intramol. cyclocondensation of o-NCCH2C6H4CH2N(COR)C6H4CO2Et-o (R = CH3, CF3) gives the title compounds I. The hydroxyl group of I is involved in a transannular hydrogen bond. The tautomerism of I was also studied. Alkylation of I (R = CH3) is accompanied by the Thorpe reaction to give dibenzofuroazocine II.
Khimiya Geterotsiklicheskikh Soedinenii published new progress about Cyclocondensation reaction, intramolecular. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Computed Properties of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics