Ionescu, Andreea; Lento, Raffaella; Mastropietro, Teresa F.; Aiello, Iolinda; Termine, Roberto; Golemme, Attilio; Ghedini, Mauro; Bellec, Nathalie; Pini, Elena; Rimoldi, Isabella; Godbert, Nicolas published the artcile< Electropolymerized Highly Photoconductive Thin Films of Cyclopalladated and Cycloplatinated Complexes>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is phenylpyridine cycloplatinated cyclopalladated Schiff base preparation electropolymerized photoconductive film; cyclopalladated cycloplatinated phenylpyridine Schiff base complex preparation electropolymerized film; electropolymerization; palladium(II) complexes; photoconductivity.
The complete characterization of novel electropolymerizable organometallic complexes is presented. These are newly synthesized cyclometalated complexes of general formula (PPy)M(O^N)n (H(PPy) = 2-phenylpyridine, M = Pd(II) or Pt(II), H(O^N)n = Schiff base). Polymeric thin films have been obtained from these complexes by electropolymerization of the triphenylamino group grafted onto the H(O^N)n ancillary ligand. The redox behavior and the photoconductivity of both of the monomers (PPy)M(O^N)n and the electropolymerized species have been investigated. The polymeric films of (PPy)M(O^N)n have shown a very significant enhancement of photoconductivity when compared to their monomeric amorphous counterparts. The high stability of the obtained films strongly suggests that electropolymerization of cyclometalated complexes represents a viable deposition technique of quality thin films with improved photoconduction properties, hence opening the door to a new class of materials with suitable properties for optoelectronic applications.
ACS Applied Materials & Interfaces published new progress about Crystal structure. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics