Crispino, Gerard A.; Jeong, Kyu Sung; Kolb, Hartmuth C.; Wang, Zhi Min; Xu, Daqiang; Sharpless, K. Barry published the artcile< Improved enantioselectivity in asymmetric dihydroxylations of terminal olefins using pyrimidine ligands>, Synthetic Route of 112-63-0, the main research area is enantioselectivity dihydroxylation olefin pyrimidine ligand; asym dihydroxylation olefin pyrimidine ligand; diol asym synthesis.
A new class of cinchona alkaloid derivatives, 2,5-diphenyl-4,6-bis(9-O-dihydroquinidyl)pyrimidine and its pseudoenantiomer 2,5-diphenyl-4,6-bis(9-O-dihydroquinyl)pyrimidine, was found to give improved enantioselectivity in the osmium catalyzed asym. dihydroxylation of mono-substituted terminal olefins. Mol. modeling and ligand structural variation studies were carried out in an attempt to understand the high enantioselectivities observed
Journal of Organic Chemistry published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Synthetic Route of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics