Yamamizu, Takafumi’s team published research in Reactive Polymers, Ion Exchangers, Sorbents in 1985-05-31 | 112-63-0

Reactive Polymers, Ion Exchangers, Sorbents published new progress about Bromination. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Quality Control of 112-63-0.

Yamamizu, Takafumi; Akiyama, Minoru; Takeda, Kunihiko published the artcile< A new styrene derivative and its application to reactive polymer synthesis>, Quality Control of 112-63-0, the main research area is divinylbenzene selective bromination; bromoethylstyrene copolymer divinylbenzene styrene; pyridinium perbromide divinylbenzene selective bromination; chain transfer bromoethylstyrene.

One of the vinyl groups of 1,3-divinylbenzene (I) [108-57-6] was selectively brominated by pyridinium hydrobromide perbromide  [39416-48-3] to form 3-(1,2-dibromoethyl)styrene (II) [95386-00-8]. The high selectivity is apparently the result of an electron-inductive effect by the 1,2-dibromoethyl group and the relatively mild activity of the brominating agent. The resulting monomer exhibits Q = 1.26 and e = 0.06 in its copolymerization with styrene. The chain-transfer constant to II was also estimated From II-styrene copolymer [95386-12-2] or I-II copolymer [97126-69-7], polymers with pendant vinyl groups were synthesized.

Reactive Polymers, Ion Exchangers, Sorbents published new progress about Bromination. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Quality Control of 112-63-0.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics