Papageorgiou, Christos; Benezra, Claude published the artcile< Synthesis of potentially allergenic chiral α-(hydroxyalkyl)acrylates>, Category: esters-buliding-blocks, the main research area is asym synthesis hydroxylalkylacrylate; acrylate hydroxyalkyl asym synthesis; sulfoxide optically active asym induction.
Treating (R)- or (S)-4-MeC6H4S(O)CHMeCO2CMe3 with Me3CMgBr and aldehydes RCH2CHO (R = Me, Bu, octyl), followed by thermal elimination, gave title compounds (R)- or (S)-Me3CO2CC(:CH2)CH(OH)CHR, resp., in 75% enantiomeric excess.
Tetrahedron Letters published new progress about Esters Role: SPN (Synthetic Preparation), PREP (Preparation). 617-55-0 belongs to class esters-buliding-blocks, and the molecular formula is C6H10O5, Category: esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics