Matousek, Vaclav; Pietrasiak, Ewa; Schwenk, Rino; Togni, Antonio published the artcile< One-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is preparation hypervalent iodine reagent; electrophilic trifluoromethylation.
Simplified syntheses suited for large scale preparations of the two hypervalent iodine reagents I and II for electrophilic trifluoromethylation are reported. In both cases, the stoichiometric oxidants sodium metaperiodate and tert-Bu hypochlorite have been replaced by trichloroisocyanuric acid. Reagent I is accessible in a one-pot procedure from 2-iodobenzoic acid in 72% yield. Reagent II was prepared via fluoroiodane III in a considerably shorter reaction time and with no need of an accurate temperature control.
Journal of Organic Chemistry published new progress about Iodanes Role: IMF (Industrial Manufacture), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics