Sui, Meng; Chen, Yong; Li, Fashe; Wang, Hua published the artcile< Study on transition metal ion Fe3+ catalyzed biodiesel oxidation and inhibition mechanism>, Product Details of C19H34O2, the main research area is transition metal ion iron catalysis biodiesel oxidation inhibition mechanism.
Me linoleate is used as an alternative component of biodiesel. The catalytic oxidation of biodiesel is studied in the presence of iron acetate using Me linoleate as the alternative component. The composition of the products obtained from the oxidation process of Me linoleate is analyzed by GC-MS and liquid phase microextraction D. functional theory is used to calculate the electronic effects of the related reactants and products, and the related catalytic oxidation reaction paths are derived. The results show that during the process of catalytic oxidation of Me linoleate in biodiesel, mainly the catalytic cracking reaction of C-H and C-C bonds and Fenton-like reaction occur. The combination of two antioxidants, TEPA and [MI][C6H2(OH)3COO], can effectively inhibit the catalytic oxidation of Cu2+ and Fe3+ and interrupt the chain reaction of the oxidation process. The neg. value of the electrostatic potential of ferric acetate is relatively large, it is obviously alk., and has a certain ability to bind with H. The irregular structure of the iron acetate unit cell makes the O-Fe bond in the mol. easy to break, which is beneficial for the catalytic oxidation process.
Fuel published new progress about Antioxidants. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Product Details of C19H34O2.
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