Eilbracht, Peter; Acker, Michael; Haedrich, Ines published the artcile< Hydrocarbonylating cyclization of dienes. 4. Regio- and stereochemistry of the cobalt- and rhodium-catalyzed synthesis of substituted cyclopentanones>, Computed Properties of 112-63-0, the main research area is hydrocarbonylation cyclization diene regiochem stereochem; cyclopentanone; rhodium cobalt catalyst hydrocarbonylation cyclization.
Carbonylation-cyclization of 1,4-dienes was studied with a number of catalysts under a variety of conditions; in some cases kinetic control allowed formation of thermodn. unfavored stereoisomers. E.g., 1,1-divinylcyclohexane with CO-H-RCo(CO)2 (R = cyclopentadiene) gave spiro ketone I and 4-MeC6H4CMe(CH:CH2)2 with, e.g., [RhCl(COD)]2-CO-H2O-MeOH gave 85% 4:1 cyclopentanones II and III.
Chemische Berichte published new progress about Alkadienes Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Computed Properties of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics