Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 415918-91-1, is researched, SMILESS is C[C@@H](N(P1OC2=CC=C3C=CC=CC3=C2C4=C5C=CC=CC5=CC=C4O1)[C@@H](C6=CC=CC=C6)C)C7=CC=CC=C7, Molecular C36H30NO2PJournal, Article, Research Support, Non-U.S. Gov’t, Angewandte Chemie, International Edition called Synthesis of allylic amines: Enantioselective allylation of aromatic amines after in situ generation of an activated cyclometalated iridium catalyst, Author is Shu, Chutian; Leitner, Andreas; Hartwig, John F., the main research direction is regioselective enantioselective allylation aromatic amine cyclometalated iridium phosphoramidite catalyst.Category: esters-buliding-blocks.
Highly regio- and enantioselective allylation of aromatic amines is observed when a cyclometalated Ir-phosphoramidite complex is generated in situ. The active catalyst can be formed from [{Ir(cod)Cl}2] and ligand L with a volatile alkylamine prior to addition of the reagents or upon use of a tertiary amine additive. E.g., a cyclometalated Ir-phosphoramidite complex catalyzed the allylation of PhNH2 by carbonate (E)-PhCH:CHCH2OC(O)OMe to give 80% (+)-PhCH(NHPh)CH:CH2.
Here is just a brief introduction to this compound(415918-91-1)Category: esters-buliding-blocks, more information about the compound((11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine) is in the article, you can click the link below.
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics