Application In Synthesis of 6H-Benzo[c]chromen-6-one. I found the field of Chemistry very interesting. Saw the article FACILE PREPARATION OF 3,4-BENZOCOUMARINS FROM 2-ARYLBENZOIC ACIDS WITH NCS AND NaI published in 2020.0, Reprint Addresses Togo, H (corresponding author), Chiba Univ, Grad Sch Sci, Inage Ku, Yayoi Cho 1-33, Chiba 2638522, Japan.. The CAS is 2005-10-9. Through research, I have a further understanding and discovery of 6H-Benzo[c]chromen-6-one.
Treatment of 2-arylbenzoic acids with N-chlorosuccinimide (NCS) and NaI at 70 degrees C under fluorescent lighting condition gave the corresponding 3,4-benzocoumarins in good yields under transition-metal-free condition. It was found that the reactivity of NCS with NaI for the formation of 3,4-benzocoumarins from 2-arylbenzoic acids was as high as that with NIS. Thus, the formation of carboxyl radicals and their cyclization onto an aromatic ring from 2-arylbenzoic acids with much less expensive NCS and NaI, than NIS could be successfully carried out to form 3,4-benzocoumarins.
Application In Synthesis of 6H-Benzo[c]chromen-6-one. Welcome to talk about 2005-10-9, If you have any questions, you can contact Nakamura, M; Togo, H or send Email.
Reference:
Article; Zhang, Jian; Shi, Dongdong; Zhang, Haifeng; Xu, Zheng; Bao, Hanyang; Jin, Hongwei; Liu, Yunkui; Tetrahedron; vol. 73; 2; (2017); p. 154 – 163;,
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