Category: esters-buliding-blocks. I found the field of Chemistry very interesting. Saw the article Methyl Trifluoroacetate as a Methylation Reagent for N-H, O-H, and S-H Functionalities under Mild Conditions published in 2019.0, Reprint Addresses Xiao, DD (corresponding author), Guangdong Univ Petrochem Technol, Coll Chem, Maoming 525000, Peoples R China.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate.
A methylation reagent for compounds bearing N-H, O-H, and S-H functionalities was developed. Methyl trifluoroacetate (MTFA) was commonly considered as trifluoroacetylating reagent or trifluoromethylating reagent. In this work, we report the methylation behavior of MTFA under mild conditions with good functional group tolerance, allowing the transformation of a wide range of substrates, including N,H-heteroaromatic compounds, phenolic compounds, carboxylic acids, thiophenols, secondary amides and imides, in high yields. This method was preliminarily applied to the chemoselective methylation of bifunctionalized secondary amide.
Category: esters-buliding-blocks. About Methyl 3-phenylpropionate, If you have any questions, you can contact Zheng, X; Zeng, JC; Xiong, MD; Huang, JW; Li, CY; Zhou, RJ; Xiao, DD or concate me.
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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