Computed Properties of C10H12O2. In 2020.0 ANGEW CHEM INT EDIT published article about BETA-KETO-ESTERS; CLICK CHEMISTRY; PHOSPHORYLATED NITRONE; ASYMMETRIC-SYNTHESIS; DICARBONYL COMPOUNDS; CATALYZED AZIDATION; HYDROGEN-PEROXIDE; ORGANIC AZIDES; ENOL ETHERS; IN-VITRO in [Uyanik, Muhammet; Sahara, Naoto; Tsukahara, Mayuko; Hattori, Yuhei; Ishihara, Kazuaki] Nagoya Univ, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan in 2020.0, Cited 91.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.
We report high-performance I+/H(2)O(2)catalysis for the oxidative or decarboxylative oxidative alpha-azidation of carbonyl compounds by using sodium azide under biphasic neutral phase-transfer conditions. To induce higher reactivity especially for the alpha-azidation of 1,3-dicarbonyl compounds, we designed a structurally compact isoindoline-derived quaternary ammonium iodide catalyst bearing electron-withdrawing groups. The nonproductive decomposition pathways of I+/H(2)O(2)catalysis could be suppressed by the use of a catalytic amount of a radical-trapping agent. This oxidative coupling tolerates a variety of functional groups and could be readily applied to the late-stage alpha-azidation of structurally diverse complex molecules. Moreover, we achieved the enantioselective alpha-azidation of 1,3-dicarbonyl compounds as the first successful example of enantioselective intermolecular oxidative coupling with a chiral hypoiodite catalyst.
Computed Properties of C10H12O2. Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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