Recently I am researching about BETA-KETO-ESTERS; CLICK CHEMISTRY; PHOSPHORYLATED NITRONE; ASYMMETRIC-SYNTHESIS; DICARBONYL COMPOUNDS; CATALYZED AZIDATION; HYDROGEN-PEROXIDE; ORGANIC AZIDES; ENOL ETHERS; IN-VITRO, Saw an article supported by the JSPS.KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [15H05755, 15H05810, 15H05484, 18H01973]; Noguchi InstituteNoguchi Memorial Institute for Medical Research; Nagoya University Graduate Program of Transformative Chem-Bio Research. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Uyanik, M; Sahara, N; Tsukahara, M; Hattori, Y; Ishihara, K. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate. Application In Synthesis of Methyl 3-phenylpropionate
We report high-performance I+/H(2)O(2)catalysis for the oxidative or decarboxylative oxidative alpha-azidation of carbonyl compounds by using sodium azide under biphasic neutral phase-transfer conditions. To induce higher reactivity especially for the alpha-azidation of 1,3-dicarbonyl compounds, we designed a structurally compact isoindoline-derived quaternary ammonium iodide catalyst bearing electron-withdrawing groups. The nonproductive decomposition pathways of I+/H(2)O(2)catalysis could be suppressed by the use of a catalytic amount of a radical-trapping agent. This oxidative coupling tolerates a variety of functional groups and could be readily applied to the late-stage alpha-azidation of structurally diverse complex molecules. Moreover, we achieved the enantioselective alpha-azidation of 1,3-dicarbonyl compounds as the first successful example of enantioselective intermolecular oxidative coupling with a chiral hypoiodite catalyst.
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Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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