Recently I am researching about C-H ACTIVATION; GRIGNARD-REAGENTS; ELECTROCYCLIC REACTIONS; CONJUGATE ADDITION; SCALABLE SYNTHESIS; ATE COMPLEXES; REACTIVITY; ALKYL; SCOPE; CYCLOISOMERIZATION, Saw an article supported by the ICIQ International Ph.D. Mobility Program (Severo Ochoa Excellence Accreditation, Spanish Ministerio de Economia y Competitividad); MPGMax Planck Society. COA of Formula: C10H12O2. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Huang, L; Gu, YT; Furstner, A. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate
In the presence of simple iron salts, 2-pyridone derivatives react with Grignard reagents under mild conditions to give the corresponding 1,6-addition products; if the reaction medium is supplemented with an aprotic dipolar cosolvent after the actual addition step, the intermediates primarily formed succumb to ring opening, giving rise to non-thermodynamic Z,E-configured dienoic acid amide derivatives which are difficult to make otherwise. Control experiments as well as the isolation and crystallographic characterization of a (tricarbonyl)iron pyridone complex suggest that the active iron catalyst generated in situ exhibits high affinity to the polarized diene system embedded into the heterocyclic ring system of the substrates, which likely serves as the actual recognition element.
Welcome to talk about 103-25-3, If you have any questions, you can contact Huang, L; Gu, YT; Furstner, A or send Email.. COA of Formula: C10H12O2
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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