Product Details of 103-26-4. Recently I am researching about LINEAR-SELECTIVE HYDROARYLATION; DIRECTING GROUPS; HYDROCARBOFUNCTIONALIZATION; CYCLIZATIONS; PALLADIUM; CLEAVAGE; ETHYLENE; HALIDES, Saw an article supported by the Shanghai Institute of Organic Chemistry, State Key Laboratory of Organometallic Chemistry, Shanghai Rising-Star Program [20QA1411400]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21821002]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Wang, DM; Feng, W; Wu, YC; Liu, T; Wang, P. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate
Reported here is the discovery of a redox-neutral Ni-II/Ni(II)catalytic cycle which is capable of the linear-selective hydroarylation of unactivated alkenes with arylboronic acids for the first time. This novel catalytic cycle, enabled by the use of an electron-rich diimine ligand, features broad substrate scope, and excellent functional-group and heterocycle compatibility under mild reaction conditions in the absence of additional oxidants and reductants. Mechanistic investigations using kinetic analysis and deuterium-labelling experiments revealed the protonation to be the rate-determining step in this redox-neutral catalysis, and the reversible chain-walking nature of the newly developed diimine-Ni catalyst.
Product Details of 103-26-4. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Wang, DM; Feng, W; Wu, YC; Liu, T; Wang, P or concate me.
Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
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