In 2020.0 CHEM-ASIAN J published article about TRANSITION-METAL-FREE; CARBON-DIOXIDE; MEDIATED CARBOXYLATION; CO2; PALLADIUM; CARBONYLATION; FUNCTIONALIZATION; ARYLPYRAZOLES; LACTONIZATION; ACTIVATION in [Saitou, Takanobu; Jin, Yushu; Isobe, Kotaro; Suga, Takuya; Takaya, Jun; Iwasawa, Nobuharu] Tokyo Inst Technol, Dept Chem, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528551, Japan in 2020.0, Cited 83.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Quality Control of Methyl 3-phenylpropionate
The Rh-catalyzed direct carboxylation of alkenyl C-H bonds was achieved by using pyrazole as a removable directing group. In the presence of 5 mol% RhCl3 . 3H(2)O, 6 mol% P(Mes)(3), and 2 equiv. of AlMe2(OMe), the alkenyl C-H bond of various alkenylpyrazoles was directly carboxylated in good yields under CO2 atmosphere. Furthermore, several useful transformations of the pyrazole moiety of the product were achieved to afford synthetically useful carboxylic acid derivatives in good yields.
Welcome to talk about 103-25-3, If you have any questions, you can contact Saitou, T; Jin, YH; Isobe, K; Suga, T; Takaya, J; Iwasawa, N or send Email.. Quality Control of Methyl 3-phenylpropionate
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics