An article Carboxylation of Aryl Triflates with CO2 Merging Palladium and Visible-Light-Photoredox Catalysts WOS:000473116000050 published article about C-H FUNCTIONALIZATION; CARBON-DIOXIDE; DUAL CATALYSIS; DRIVEN CARBOXYLATION; UNACTIVATED PRIMARY; BUILDING-BLOCK; BONDS; HALIDES; ACIDS; HYDROCARBOXYLATION in [Bhunia, Samir Kumar; Das, Pritha; Nandi, Shantanu; Jana, Ranjan] CSIR Indian Inst Chem Biol, Organ & Med Chem Div, 4 Raja SC Mullick Rd, Kolkata 700032, W Bengal, India; [Bhunia, Samir Kumar; Jana, Ranjan] Acad Sci & Innovat Res AcSIR, Kolkata 700032, W Bengal, India in 2019.0, Cited 88.0. The Name is 6H-Benzo[c]chromen-6-one. Through research, I have a further understanding and discovery of 2005-10-9. Computed Properties of C13H8O2
We report herein a visible-light-promoted, highly practical carboxylation of readily accessible aryl triflates at ambient temperature and a balloon pressure of CO2 by the combined use of palladium and photoredox Ir(III) catalysts. Strikingly, the stoichiometric metallic reductant is replaced by a nonmetallic amine reductant providing an environmentally benign carboxylation process. In addition, one-pot synthesis of a carboxylic acid directly from phenol and modification of estrone and concise synthesis of pharmaceutical drugs adapalene and bexarotene have been accomplished via late-stage carboxylation reaction. Furthermore, a parallel decarboxylation-carboxylation reaction has been demonstrated in an H-type closed vessel that is an interesting concept for the strategic sector. Spectroscopic and spectroelectrochemical studies indicated electron transfer from the Ir(III)/DIPEA combination to generate aryl carboxylate and Pd(0) for catalytic turnover.
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Reference:
Article; Zhang, Jian; Shi, Dongdong; Zhang, Haifeng; Xu, Zheng; Bao, Hanyang; Jin, Hongwei; Liu, Yunkui; Tetrahedron; vol. 73; 2; (2017); p. 154 – 163;,
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