An article para-Selective arylation and alkenylation of monosubstituted arenes using thianthrene S-oxide as a transient mediator WOS:000532500300017 published article about CATALYZED DIRECT ARYLATION; C-H ACTIVATION; ARYL BOND FORMATION; PALLADIUM; FUNCTIONALIZATION; (HETERO)ARENES; BENZAMIDES; ANILIDES; BENZENE; ACID in [Chen, Xiao-Yue; Nie, Xiao-Xue; Wu, Yichen; Wang, Peng] Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China; [Wang, Peng] Chinese Acad Sci, Shanghai Inst Organ Chem, CAS Key Lab Energy Regulat Mat, 345 Lingling Rd, Shanghai 200032, Peoples R China in 2020.0, Cited 54.0. COA of Formula: C10H12O2. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3
Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki-Miyaura coupling sequence under mild conditions. This reaction features a broad substrate scope, and functional group and heterocycle tolerance. The versatility of this approach was further demonstrated by late-stage functionalization of complex bioactive scaffolds, and direct synthesis of some pharmaceuticals, including Tetriprofen, Ibuprofen, Bifonazole, and LJ570.
Welcome to talk about 103-25-3, If you have any questions, you can contact Chen, XY; Nie, XX; Wu, YC; Wang, P or send Email.. COA of Formula: C10H12O2
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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