Recently I am researching about ELECTROCHEMICAL REDUCTION; ALKENES; DICHLORINATION; FUNCTIONALIZATION; HALOGENATION; 4′-NITROBENZENESULFENANILIDE; DIBROMINATION; BROMINATION; REMEDIATION; BROMIDE, Saw an article supported by the European Research Council under the European Union’s Horizon 2020 research and innovation program [757608]; ETH ZurichETH Zurich; Marie Sklodowska-Curie Action (HaloCat) [886102]; DFG fellowship by the Graduate School Materials Science in MainzGerman Research Foundation (DFG) [GSC 266]. Published in AMER ASSOC ADVANCEMENT SCIENCE in WASHINGTON ,Authors: Dong, XC; Roeckl, JL; Waldvogel, SR; Morandi, B. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate. COA of Formula: C10H10O2
Vicinal dibromides and dichlorides are important commodity chemicals and indispensable synthetic intermediates in modern chemistry that are traditionally synthesized using hazardous elemental chlorine and bromine. Meanwhile, the environmental persistence of halogenated pollutants necessitates improved approaches to accelerate their remediation. Here, we introduce an electrochemically assisted shuttle (e-shuttle) paradigm for the facile and scalable interconversion of alkenes and vicinal dihalides, a class of reactions that can be used both to synthesize useful dihalogenated molecules from simple alkenes and to recycle waste material through retro-dihalogenation. The reaction is demonstrated using 1,2-dibromoethane, as well as 1,1,1,2-tetrachloroethane or 1,2-dichloroethane, to dibrominate or dichlorinate, respectively, a wide range of alkenes in a simple setup with inexpensive graphite electrodes. Conversely, the hexachlorinated persistent pollutant lindane could be fully dechlorinated to benzene in soil samples using simple alkene acceptors.
About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Dong, XC; Roeckl, JL; Waldvogel, SR; Morandi, B or concate me.. COA of Formula: C10H10O2
Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
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