Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Kohsaka, Yasuhiro, once mentioned the application of 924-99-2, Name is Ethyl 3-(dimethylamino)acrylate, molecular formula is C7H13NO2, molecular weight is 143.1836, MDL number is MFCD00144269, category is esters-buliding-blocks. Now introduce a scientific discovery about this category, Formula: C7H13NO2.
Degradable and curable poly(conjugated ester)s prepared by acryl- and conjugate-substitutions of the ‘smallest’ monomer
alpha-(Chloromethyl)acryloyl chloride was polymerized with various bisphenols and diamines to yield poly(conjugated ester)s. The polymer prepared from bisphenol Z underwent curing by heating at 170 degrees C, while copolymerization with methyl methacrylate afforded a crosslinked polymer. The poly(conjugated ester)s were chemically decomposed via main-chain scission by the conjugate substitution with benzyl mercaptan. Moreover, the treatment with 5 wt% aqueous ammonia resulted in complete main-chain scission to the monomeric units by conjugate substitution and acyl substitution reaction, recovering bisphenol Z. Although curing and main-chain scission resulted in contractive changes on polymer properties, both reactions were achieved by a same skeleton, alpha-(aryloxymethyl)acrylate. Thus, alpha-(chloromethyl)acryloyl chloride is the smallest monomer to incorporate such a curable and degradable skeleton.
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